IJSR - International Journal of Scientific Research

B. Akila; A. Xavier

Volume : VIII, Issue : VIII, August - 2019

Biological studies of newly Synthesis of (1Z, 1‘Z)–N, N‘–(ethane–1, 2–diylbis(oxy))bis(5–methoxy–2,1–phenylene)bis(1–(2–bromo–4–flourophenylmethanimine and its transition metal complexes.

B. Akila, A. Xavier

Abstract :

This work involved the synthesis of narrative new Schiff base or azomethine group and its metal complexes of [Ru (III), Cu (II), Co (II) and Mn (II)]. The azomethine functional group formed with the coupling of 2, 5– Dimethoxy Aniline and 2–omo–4–fluoro benzaldehyde (L4). The molar ratio of Ligand–metal is 1:1.The structure and geometrical elucidation using 1H–NMR, 13C–NMR, electronic absorbance spectroscopy, FT–IR spectroscopy, Spectroflurometer. The molecular weight of ligand and metal complexes is confirmed by mass spectrum. The ligand gets dimerized nature. Investigation of the biological activity of anti–microbial and antioxidant studies of metal complexes is more active than free ligand. The interaction of metal complexes with calf thymus DNA (CT–DNA) was carried out by absorption technique