Volume : VIII, Issue : II, February - 2019

Oxidation of Hydroquinone By N-Chloropiperazine-2,5-Dione-Kinetic and Mechanistic study

K. Rajalakshmi

Abstract :

The kinetics and mechanism of oxidation of Hydroquinone, 8–Hydroxyquinoline and Hydroxylamine was studied by N–Chloropiperazine–2, 5–dione in acetic acid–water medium. The reaction was found in Hydroquinone and 8–Hydroxyquinoline to be one with respect to [oxidant] and fractional order with respect to [substrate]. The reactions are studied at five different temperatures. The enthalpy of activation and entropy of activation are calculated. Based on the above kinetic facts, a suitable mechanism was proposed for each substrate

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Article: Download PDF   DOI : 10.36106/ijsr  

Cite This Article:

OXIDATION OF HYDROQUINONE BY N-CHLOROPIPERAZINE-2,5-DIONE-KINETIC AND MECHANISTIC STUDY, K.Rajalakshmi INTERNATIONAL JOURNAL OF SCIENTIFIC RESEARCH : Volume-8 | Issue-2 | February-2019

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