Volume : VII, Issue : II, February - 2018

Oxidative transformation of propan–1–ol with pcc in acetonitrile

Kirti Motwani Ahuja, B K Dangarh, Neetu Shorgar

Abstract :

 

Kinetic mechanism was investigated for oxidative transformation of propan–1–ol is done by pcc in acetonitrile. PTSA was used as donner of [H⁺] and reaction was carried out at 308 ℃ temperature. Rate of reaction was examined for various concentration of PTSA, substrate. Reaction rate was also accomplished for different solvent compositions. The change in dielectric constant can vary the rate. All experiments were operated at 360 nm optical density. Thermodynamic parameters were evaluated and a mechanism was proposed. Propan–1–ol gives corresponding aldehyde after oxidation.

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Article: Download PDF   DOI : 10.36106/ijsr  

Cite This Article:

Kirti Motwani Ahuja, B K Dangarh, Neetu Shorgar, Oxidative transformation of propan-1-ol with pcc in acetonitrile, INTERNATIONAL JOURNAL OF SCIENTIFIC RESEARCH : Volume-7 | Issue-2 | February-2018

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