Complexes of silver (I) perchlorate and mercury (II) halides with some tertiary arsines

Manuchar Chikovani; Maia Rusia

Volume : VI, Issue : VIII, August - 2016

Complexes of silver (I) perchlorate and mercury (II) halides with some tertiary arsines

Manuchar Chikovani, Maia Rusia

Abstract :

The interaction of silver (I) perchlorate and mercury (II) halides with triaryl– and diarylalkyl arsines was studied. As a result the complex compounds were obtained having the following formulas and ,were ; , , , , , . Both the elemental and physicochemical analysis were applied to study composition and structure of the received compounds.Coordination formulas were established by measuring molar conductivity of the synthesized compounds solved in DMF (dimethylformamide). The molar conductivity of silver (I) tetra (triaryl– and diarylalkyl) arsine perchlorates ranges within 62–71 Om–1?cm2?mol–1 which corresponds to molar conductivity of doubleion type electrolytes. As for complexes of mercury (II) chloride and omide with tertiary arsines, their molar conductivity does not exceed 30 Om–1?cm2?mol–1 , which proves the compounds being the nonelectrolytes. Study of the infrared spectrum as well as thermal and elemental analysis of the synthesized complex compounds were conducted.