Volume : VII, Issue : VI, June - 2017

Studies Of Zinc (II), Cadmium (II) & Lead (II) Complexes Of N–(5–Bromo–Napthyl)–2– Mercapto Propanamide & N–(5–Methoxy Napthyl)–2–Mercapto Propanamide Macro Organic Ligands

V. K. Pathak, P. R. Pandey

Abstract :

 Some novel complexes of ligands N – (5–Bromo–Napthyl) –2– mercapto propanamide and N– (5–methoxy Napthyl) –2– mercapto propanamide with Zn(II), Cd(II) and Pb(II) were prepared. The ligands and their metal complexes were characterized by Physico – chemical spectroscopic techniques. The spectral data suggested the deprotonation of thiol (–SH) group and its coordination to the metal ions in complexes. It was also suggested to involve NH group in coordination to the metal ion through nitrogen atom. Further, spectroscopic studies suggested tetrahedral, octahedral Zn(II) complexes, tetrahedral, distorted octahedron Cd(II) complexes and square pyramidal geometry Pb (II) complexes.

Keywords :

Article: Download PDF   DOI : 10.36106/ijar  

Cite This Article:

Number of Downloads : 666

References :

References 1. Kato M., Jonassen H.B. and Fanning J.C.: Chem. Rev., 64, 99, (1964). 2. Martin R. L. and water man H. : J. Chem S0C, A, 2545 (1957) 3. Billing D.E., underhill A.E., Adams D.M. and morris D.M. : J. Chem. soc, A, 1671 (1957). 4. Syamal A., Kata K.S. and Banerjee S. : J. Ind . Chem S0C. LV, 599, (1978). 5. Okaw H., Kida S., Takao A., Sasaki M. and Tanaka M.: J . Inorg. Nucl. Chem., 39, 1569 (1977). 6. Figgis B.N. : “Introduction to Ligand Field theory”, Interscience Publishers, Inc, New york (1966). 7. Baevers C.A. and Lipson L.: Proc. Roy–SOC. (London), A. 146, 510 (1934). 8. Holmes O.G. and Mc clure I.S. : J. Phys, Chem, 26, 1686, (1957). 9. Jerrum J.B., Ballhausen C.J. and Jorgensen C.J. Acta. Chem. Scand 8, 1275, (1954). 10. Forster E. and Good game D.M. : J. chem., soc., 2790 (1964). 11. Wiberley S.E., Baner W.H. and Bunee S.C.: Anal, Chem, 32, 217, (1960). 12. Lebas J.M. and Josien M.C. : Bull . soc. Chim. France, 53, 57, 62, (1956). 13. Lagrange C. Caorigou, Labas J.M. and Josien M.L.: spectro. Chim. Acta., 15, 225, (1959). 14. Duvall R.B., Young C.W. and Wrignt N. : Anal. Chem., 23, 709 (1951). 15. Whilfen D.H.: Spectro Chim., Acta., 7, 253 (1955) 16. Bunce S C., Wiberley S.E. and Baner W.H.: Anal., Chem. 32, 217 (1960). 17. 17. Cleveland F.F and Muray M.J.: J. Cm, Chem, soc, 63, 1718, (1941). 18. Thornton V. and Me Murry H.L.: Anal, Chem., 24,318, (1952). 19. Metesseu Gh. D. and Avram M. Infrared spetroscopy, wiley – interscience P–207 (1976). 20. Kitritzky A.R.: Quart Rev 13, 353 (1959). 21. Bunce S.C., Wiberley S.E. and Baner W.H.: Anal, Chem, 32, 217, (1960). 22. Ahuja I.S.: J. Inorg. chem., 29, 2091 (1967). 23. Good game M. and Flint C.D.: J. Chem soc. A. 1718 (1967). 24. Hambright P., Talbrt P.T., Kang E., Weaver J.A. and Torpe A.T.: Inorg., Chem., 9, 268, (1970). 25. Kristrita M., Inove M. and Kube M.: Inorg. Chem., 3, 237, 239, (1964). 26. Nortis : Sonmenkem, 33, 161, (1960). 27. Dum T.M., Mc clure D.S. and Pearson R.G.: “some Aspects of crystal Field Theory”, Harper and Rowpu. 28. Ball Hausen C.J.: “Introduction to Ligand Field Theory” Mc Graw Hill, Newyork, 268 (1962). 29. Kaliuti Y.: J. Chem., Phys., 25(4), 777 (1950). 30. Keisar W.E., Alpert N.L. and Szymanski H.A. : I.R. Theory and Practice of Spectroscopy, Roselta Ed. P–261 (1970). 31. Meteescu Gh. D and Avram M.: Infrared spectroscopy wiley – Interscience, P–207 (1976). 32. Shayma A.S. , Yang F. and Abbas A.S.,: European Journal of Scientic Research,33: 702,(2009). 33. Shayma A.S. and Yang F. : American Journal of Scientic Research,5: 20, (2009). 34. Shayma A.S.,Synthesis, : E–Journal of Chemistry,(in press),7(5),(2010). 35. Harlai S. and Varshney A.K.,Synthesis,: Bioinorganic Chem Appl: 1,(2006). 36. Bian J., Chang Y. and Zhang J.: Journal of Physical Chemistry A, 112, 14, 3186–3191, (2008). 37. Klapotke T.M., Stierstorfer J. and Wallek A.U.: Chemistry of materials, 20, 13, 4519– 4530, (2008). 38. Mayhall N.J., Raghavachari K., Redfern P.C., and Curtiss L.A.: Journal of Physical Chemistry A, 113, 17, 5170–5175, (2009). 39. Chachkov D.V. and Mikhailov O.V.: Russian Journal of Inorganic Chemistry, 54, 12,1952–1956, (2009). 40. Cotton F.A. and Wilkinson G., Advanced Inorganic Chemistry. Wiely inter science, New York, (1998). 41. Dallali N. and Agrawal Y.K.: Iran J. Chem. And Chem. Eng., 23:65,(2004). 42. Karbeng C., Tarafder M. T.H., Karen A.C., Ali A.M , Yamin B.M., Fun H.K.: 23:1385,(2004). 43. Neto J.L., Delima G.M. and Berldo H.: Spectrochimica Acta part A., 63:669,(2006). 44. Papia C., Harji T.K.D., Agrawala B.V. and Arun K.D.: J. Indian Chem. Soc., 66:550,(1989). 45. Klich P.R., Daniher A.T., Challen P.R., McConville D.B., Youngs W.J., Inorg.Chem.35,347,(1996). 46. Mondal S., Rath S.P., Rajak K.K., Chakravorty A., Inorg.chem.37,1713,(1998) 47. Agrawal U.and Khullar IP.:Kah.J.Chem 53,1165(1975). 48. Larkworthy L.F, Murphy J.M. and Philips D.J.: Inorg. Chem : 7,1436(1968). 49. Ali Akbar, Mirza M., VOO A.H., Tan C.W, Bernhardt A.L, P.V. : Polyhedron,22,3433,– 34.38(2003).